Hardness is dissolved calcium and magnesium, picked up from limestone and chalk. It is set by the geology under your area and cannot be changed by your water company. It is also the water property people notice most — in kettles, on shower screens, and in how much detergent it takes to get a lather.

How limescale forms

Limescale is calcium carbonate coming back out of solution. Heating is what does it, which is why kettles and heating elements scale and cold pipes generally do not.

How limescale formsHard water contains dissolved calcium and bicarbonate. When heated, bicarbonate decomposes into carbonate, carbon dioxide and water. The carbon dioxide escapes as gas, and the carbonate combines with calcium to form solid calcium carbonate, which deposits on the hottest surfaces. A scaled heating element transfers heat less efficiently and uses more energy for the same result.Hard waterCa²⁺ + 2HCO₃⁻Heatingabove ~60 °CCO₂ escapesCaCO₃ depositslimescaleH₂O remainsHeating elementreduced efficiency
The reaction
Ca(HCO₃)₂ → CaCO₃ (solid) + CO₂ (gas) + H₂O. Heat drives it to the right.
Why only temporary hardness scales
Only bicarbonate-associated hardness decomposes on heating. Sulphate and chloride hardness stays in solution.
Removal
Descaling with a weak acid — citric or acetic — dissolves it back. Softening prevents it by removing the calcium first.

Why heating causes it

Hard water contains calcium paired with bicarbonate. Heating decomposes the bicarbonate, releases carbon dioxide, and leaves calcium carbonate — which is not very soluble and comes out as solid scale on the hottest surface available.

That is why kettles, immersion heaters, boilers and shower heads scale while cold pipes generally do not. The scale in your kettle is, quite literally, the limestone the water dissolved on its way to you.

What it costs

  • Scale on a heating element insulates it, so the appliance uses more energy for the same result
  • Shortened life for kettles, washing machines, dishwashers and boilers
  • More detergent and soap needed, because hardness reacts with them to form the scum that leaves tide marks
  • Blocked shower heads and aerators

What actually works

Hardness treatment options
OptionDoes it work?Trade-off
Ion exchange softenerYes — removes hardness completelyAdds sodium; needs salt and regeneration; discharges brine to the sewer
Reverse osmosis at the tapYes — removes hardness and most elseSlow; wastes water; only treats one tap
Descaling with citric or acetic acidYes — dissolves scale that has already formedReactive rather than preventive; needs repeating
Scale inhibitor dosing (polyphosphate)Partly — keeps scale in suspension rather than removing hardnessCheap and simple; does not soften the water
Electromagnetic and magnetic descalersEvidence is weak and inconsistentIndependent trials have not reproduced manufacturer claims. Some users report an effect; controlled studies largely do not
BoilingNo, in any useful senseIt precipitates the scale rather than removing hardness — the scale ends up in the kettle
Uncertain
Magnetic and electronic descalers soften water.

These devices do not remove calcium or magnesium, so they do not soften water in the chemical sense — that much is not in dispute. The claim is that they alter crystal formation so scale does not adhere. Some laboratory studies report an effect on crystal morphology; independent field trials have largely failed to reproduce a consistent practical benefit. The honest position is that the evidence does not support the marketing, without asserting that no effect exists.

If you install a softener

Ion exchange softening swaps calcium and magnesium for sodium — roughly 46 mg/l of sodium for every 100 mg/l of hardness removed. In a very hard water area that is a meaningful addition, and it is why softened water is conventionally not plumbed to the kitchen drinking tap. Leave one hard tap for drinking and cooking.

Softer water is also more plumbosolvent, so in a property with lead pipework softening can increase lead pickup. That is a further reason to keep the drinking tap unsoftened.

Size a softener and see the sodium it adds

Open the calculator

Sources

More on tap water