Calcium

The dominant cation in most fresh water and the principal contributor to hardness. Calcium is where limescale comes from, and also the main reason mineral waters differ in taste.

Magnesium

The second contributor to hardness, and the one that gives some mineral waters a distinctly bitter edge.

Sodium

Present from geology, sea spray, road salt and — importantly — from ion exchange water softening, which removes hardness by substituting sodium for calcium and magnesium.

Bicarbonate

The dominant anion in most fresh waters and the source of nearly all alkalinity. Bicarbonate is the reason hard water scales when heated.

Chloride

A conservative ion that moves with water essentially unchanged, which makes it a useful tracer of saline intrusion, road salt and wastewater influence.

Iron

One of the most common causes of consumer complaint, producing orange or brown discoloured water and staining laundry, without generally posing a health risk at the concentrations involved.

Sulphate

Contributes permanent hardness and, at higher concentrations, a bitter taste and a laxative effect that is the basis of several historic spa waters.

Manganese

Behaves similarly to iron but stains black rather than orange, and is harder to oxidise. Increasingly treated as a health parameter as well as an aesthetic one.

Potassium

Usually a minor constituent of fresh water, since it is readily taken up by plants and clay minerals.

Silica

Dissolved silicon, present in almost all natural water and a persistent operational problem for membranes and boilers because it forms a hard, difficult scale.