Agricultural runoff pathways
Nutrients and pesticides reach water by several routes with very different timescales — which is why land management changes take decades to show up in groundwater.
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Fertiliser and manure applied to fields reach water three ways. Surface runoff carries phosphorus attached to soil particles into streams within hours of heavy rain. Field drains carry dissolved nitrate to watercourses within days. Leaching carries nitrate down through the soil and unsaturated zone into groundwater, taking years to decades. Each pathway delivers different pollutants on a different timescale.